Product ID:SODIUM FLUORIDE (SEE SUPPL DATA)
MSDS Date:07/10/2000
FSC:6810
NIIN:00-680-1079
Status Code:A
MSDS Number: CKSVQ

Emergency Phone: 425-889-3400

Info Phone: 425-889-3400/425-889-3617

Preparer: MSDS COORDINATOR

Cage: 0STM5

Telephone: 510-535-1266

Cage: 0V485

SODIUM FLUORIDE

CAS: 7681-49-4

RTECS: WB0350000

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:ORAL RAT LD50: 52 MG/KG
Routes of Entry: Inhalation:YES Skin:UNKNOWN Ingestion:YES
Health Hazards Acute and Chronic:INHALATION: CAUSES SEVERE IRRITATION
TO THE RESPIRATORY TRACT. MAY BE ABSORBED THROUGH INHALATION OF
DUST. IRRITATION EFFECTS MAY NOT APPEAR IMMEDIATELY. INGESTION:
TOXIC ! MAY CAUSE BRAIN & KIDNEY DA MAGE. AFFECTS HEART &
CIRCULATORY SYSTEM. DEATH MAY OCCUR FROM RESPIRATORY PARALYSIS.
ESTMIATED LETHAL DOST = 5 TO 10 GRAMS. SKIN: CAUSES IRRITATION.
SOLUTIONS ARE CORROSIVE. EFFECTS MAY NOT APPEAR I MMEDIATELY. EYE:
IRRITANT ! MAY CAUSE IRRITATION & SERIOUS EYE DAMAGE. EFFECTS MAY
NOT IMMEDIATELY APPEAR. CHRONIC: MAY CAUSE MOTTLING OF TEETH & BONE
DAMAGE (OSTEROCLEROSIS) & FLUOROSIS.
Explanation of Carcinogenicity:NONE PROVIDED BY MFR.
Effects of Overexposure:INHALATION: COUGHING, SORE THROAT & LABORED
BREATHING. MAY PARALLEL THOSE FROM INGESTION EXPOSURE. INGESTION:
MAY CAUSE SALIVATION, NAUSEA, VOMITING, DIARRHEA, & ABDOMINAL PAIN.
SYMPTOMS OF WEAKNESS, TREMORS, SHALLOW RESPIRATION, CARDOPEDAL
SPASM, CONVULSIONS, & COMA MAY FOLLOW. SKIN: REDNESS & PAIN.
CHRONIC: SYMPTOMS OF FLUORISIS INCLUDE BRITTLE BONES, WEIGHT LOSS,
ANEMIA, CALCIFIED LIGAMENTS, G ENERAL ILL HEALTH & JOINT STIFFNESS.
Medical Cond Aggravated by Exposure:POPULATIONS THAT APPEAR TO BE AT
INCREASED RISK FROM THE EFFECTS OF FLUORIDE ARE INDIVIDUALS THAT
SUFFER FROM DIABETES INSIPIDUS OR SOME FORMS OF RENAL IMPAIRMENT.

First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
CALL A PHYSICIAN IMMEDIATELY. INGESTION: ADMINISTER MILK, CHEWABLE
CALCIUM CARBO NATE TABLETS OR MILK OF MAGNESIA. NEVER GIVE ANYTHING
MY MOUTH TO AN UNCONSCIOUS PERSON. CALL A PHYSICIAN IMMEDIATELY.
SKIN: WIPE OFF ANY EXCESS MATERIAL FROM SKIN & THEN IMMEDIATELY
FLUSH SKIN WITH L G AMOUNTS OF SOAPY WATER. REMOVE CONTAMINATED
CLOTHING & SHOES. WASH CLOTHING BEFORE RE-USE. APPLY BANDAGES
SOAKED IN MAGNESIUM SULFATE. CALL A PHYSICIAN IMMEDIATELY.

Flash Point:NONE PROVIDED BY
Lower Limits:NONE PROVIDE
Upper Limits:NONE PROVIDE
Extinguishing Media:NOT CONSIDERED TO BE A FIRE HAZARD. USE ANY MEANS
SUITABLE FOR EXTINGUISHING SURROUNDING FIRE.
Fire Fighting Procedures:IN THE EVENT OF A FIRE, WEAR FULL PROTECTIVE
CLOTHING & NIOSH-APPROVED SELF CONTAINED BREATHING APPARATUS WITH
FULL FACEPIECE OPERATED IN THE PRESSURE DEMAND OR OTHER POSITIVE
PRESSURE MODE.
Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE AN EXPLOSION
HAZARD.

Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. WEAR
APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. SPILLS: PICK UP & PLACE
IN A SUITABLE CONTAINER FOR RECLAMATION OR DISPOSAL, USING A METHOD
THAT DOES NOT GENERATE DUST . US REGULATIONS (CERCLA) REQUIRE
REPORTING SPILLS & RELEASES TO SOIL, WATER & AIR IN EXCESS OF
REPORTABLE QUANTITIES. THE TOLL FREE NUMBER FOR THE US COAST GUARD
IS 800-424-8802
Neutralizing Agent:NONE PROVIDED BY MFR.

Handling and Storage Precautions:KEEP IN A TICHTLY CLOSED CONTAINER,
STORE IN A COOL, DRY VENTILATED AREA. PROTECT AGAINST PHYSICAL
DAMAGE. SEPARATE FROM ACIDS & OXIDIZING MATERIALS. CONTAINERS OF
THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTY SINCE THEY RETAIN
PRODUCT RESIDUES (DUST, SOLIDS); OBSERVE ALL WARNINGS & PRECAUTIONS
LISTED
Other Precautions:NONE PROVIDED BY MFR.

Respiratory Protection:IF THE EXPOSURE LIMIT IS EXCEEDED, A HALF-FACE
DUST/MIST RESPIRATOR MAY BE WORN FOR UP TO TEN TIMES THE EXPOSURE
LIMIT OR THE MAXIUM USE CONCENTRATION SPECIFIED BY THE APPROPRIATE
REGULATORY AGENCY OR RESPIRATOR SUPPLIER, WHICHEVER IS LOWEST. A
FULL-FACE PIECE DUST/MIST RESPIRATOR MAY BE WORN UP TO 50 TIMES THE
EXPOSURE LIMIT, OR THE MAXIUM USE CONCENTRATION
Ventilation:A SYSTEM OF LOCAL &/OR GENERAL EXHAUST IS RECOMMENDED TO
KEEP EMPLOYEE EXPOSURES BELOW THE AIRBORNE EXPOSURE LIMITS. LOCAL
EXHAUST VENTILATION IS GENERALLY PREF
Protective Gloves:WEAR IMPERVIOUS PROTECTIVE GLOVES
Eye Protection:CHEMICAL SAFETY GOGGLES &/OR FULL FACE SHIELD
Other Protective Equipment:WEAR IMPERVIOUS PROTECTIVE CLOTHING,
INCLUDING BOOTS, GLOVES. LAB COAT, APRON OR COVERALLS, AS
APPROPRIATE, TO PREVENT SKIN CONTACT. MAINTAIN EYE WASH FOUNTAIN &
QUICK-DRENCH FACILITIES IN WORK AREA.
Work Hygienic Practices:NONE PROVIDED BY MFR.
Supplemental Safety and Health
VENDOR'S P/N: X-D680. P/N: SYNONYMS: FLORIDINE, SODIUM MONOFLUORIDE,
DISODIUM DIFLUORIDE; NATRIUM FLUORIDE; FLOROCID.

HCC:T4
Boiling Pt:=1700.C, 3092.F
Melt/Freeze Pt:=992.8C, ######F
Decomp Temp:Decomp Text:NONE PROVIDED BY MFR.
Vapor Pres:1 @ 1077C(1971F) (MM HG)
Vapor Density:NO INFO
Spec Gravity:2.78
pH:NO INFO FOUND
Viscosity:NONE PROVIDED BY MFR.
Evaporation Rate & Reference:NO INFORMATION FOUND
Solubility in Water:4 G/100 ML WATER @ 15C
Appearance and Odor:WHITE CRYSTALS, ODORLESS
Percent Volatiles by Volume:0 @ 21C(70F)
Corrosion Rate:NONE PROVIDED BY MFR

Stability Indicator/Materials to Avoid:YES
REACTS WITH ACIDS TO FORM HYDROGEN FLUORIDE
Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE &
STORAGE
Hazardous Decomposition Products:BURNING MAY PRODUCE HYDROGEN FLUORIDE
VAPORS
Conditions to Avoid Polymerization:WILL NOT OCCUR

Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY OR
RECYCLING SHOULD BE MANAGED IN AN APPROPRIATE & APPROVED WASTE
DISPOSAL FACILITY. PROCESSING, USE OR CONTAMINATION OF THIS PRODUCT
MAY CHANGE THE WASTE MANAGEM ENT OPTIONS. STATE & LOCAL DISPOSAL
REGULATIONS MAY DIFFER FROM FEDERAL DISPOSAL REGUALTIONS.

Toxicological Information:ORAL RAT LD50=52 MG/KG; EYE RABBIT (STANDARD
DRAIZE) 20 MG/24 HR, MODERATE; INVESTIGATED AS TUMORIGEN, MUTAGEN,
REPRODUCTIVE EFFECTOR: NTP AND IARC = NO.

Ecological:NO INFORMATION FOUND.

Transport Information:PSN: SODIUM FLUORIDE, SOLID, 6.1, UN1690, III.

SARA Title III Information:CERCLA SECTION 103 (40CFR302.4): N SARA
SECTION 302 (40CFR355.30):RQ AND TPQ=NO. SARA SECTION 313
(40CFR372.65): N0 SARA HAZARD CATEGORIES, SARA SECTIONS 311/312
(40CFR370.21): ACUTE: Y., CHRONIC: YES., FIRE: NO. REACIVITY
= NO. CERCLA RQ = 1,000 LBS.
Federal Regulatory Information:LISTED ON THE CHEMICAL INVENTORY LIST OF
TSCA, EC, JAPAN AND AUSTRALIA.
State Regulatory Information:AUSTRALIAN HAZCOM CODE: 2Z. POISON
SCHEDULE ; S2.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.